Ceramic Membrane Immobilized Chiral Di-chloromethyl Salen-Co Catalyst and Its Use in HKR of Racemic Epichlorohydrin
نویسندگان
چکیده
منابع مشابه
Chiral (salen)Co(III) catalyst for the synthesis of cyclic carbonates.
A catalyst system comprised of a Co(III)(salen) complex and a Lewis base is investigated for the reaction of CO2 and a variety of epoxides to form cyclic carbonates. Application of this catalyst system in the kinetic resolution of propylene oxide is also discussed.
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The solid catalyst with high catalytic activity and enantioselectivity in the hydrolytic kinetic resolution (HKR) of epoxides was prepared by confining Co(Salen) in the nanocage of SBA-16 through reducing the pore entrance size using a silylation method. It was found that the activity of the solid catalysts increased with the number of [Co(Salen)] molecules per nanocage increasing, and the soli...
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The (salen)Co(III)-catalyzed hydrolytic kinetic resolution (HKR) of terminal epoxides is a bimetallic process with a rate controlled by partitioning between a nucleophilic (salen)Co-OH catalyst and a Lewis acidic (salen)Co-X catalyst. The commonly used (salen)Co-OAc and (salen)Co-Cl precatalysts undergo complete and irreversible counterion addition to epoxide during the course of the epoxide hy...
متن کاملHighly selective hydrolytic kinetic resolution of terminal epoxides catalyzed by chiral (salen)Co(III) complexes. Practical synthesis of enantioenriched terminal epoxides and 1,2-diols.
The hydrolytic kinetic resolution (HKR) of terminal epoxides catalyzed by chiral (salen)Co(III) complex 1 x OAc affords both recovered unreacted epoxide and 1,2-diol product in highly enantioenriched form. As such, the HKR provides general access to useful, highly enantioenriched chiral building blocks that are otherwise difficult to access, from inexpensive racemic materials. The reaction has ...
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The technique to fabricate nanofibrous mat by electro-spinning has been known for a long time. But the attempts to use the electospun nanofiber mats, also known as electro-spun nanofiber membranes (ENMs), for filtration purposes began only recently. Among many membrane filtration processes, air cleaning by the removal of dust particles has already been commercialized and the product has been in...
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ژورنال
عنوان ژورنال: DEStech Transactions on Engineering and Technology Research
سال: 2017
ISSN: 2475-885X
DOI: 10.12783/dtetr/apetc2017/11066